By Anthony Mallet
The prior decade has noticeable large advances within the kinds and functions of mass spectrometry in all parts of technology. With this development has come a bewildering array of names, technical phrases and abbreviations, making it a problem to maintain up-to-date.This Dictionary is a kick off point for all these new to the subject, in addition to a useful reference on terminology for these already within the box. absolutely illustrated in complete color, the Dictionary will relief scientists from all disciplines in turning into acquainted with the language and terminology of mass spectrometry.The Dictionary could be an important reference resource for:experienced clients as an aide memoir or while looking explanation of terminologypurchasers of apparatus who desire a proof of the technical phrases utilized in manufacturer's brochures and manualspotential MS clients who desire a definition of an strange tool or procedure.
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Diaphragm vacuum pump Diaphragm gauge. Courtesy of INFICON Limited, Liechtenstein 40 A single-stage or multistage dry compressing vacuum pump that is oil free. A tensioned diaphragm is moved in an oscillating manner, increasing and decreasing the volume of the pumping chamber to produce the pumping action. dication dication A doubly-charged ion formed by the loss of two electrons from a neutral species, such as Ca2+ or [C24H12]2+. dielectric barrier discharge ionisation (DBDI) A form of ambient ionisation in which a discharge electrode is positioned above a glass slide placed on top of a copper sheet electrode.
For peptide mixtures, data-dependent MS/MS spectra are recorded in real time for the n most intense ions in a mass spectrum, where n is defined by the analyst. In other cases, spectra are recorded when the intensity of a particular ion signal exceeds a threshold value. data processing A term for any kind of data analysis in which the data from the MS detector is manipulated to produce results. This is generally carried out by automated procedures and includes such operations as thresholding, peak centroiding, noise reduction, peak finding and deconvolution.
De Hoffmann and V. Stroobant, p 144, © John Wiley & Sons, Ltd An analyser that focusses ions according to their kinetic energies. A spread of kinetic energies in the formation of ions in a mass spectrometer source leads to a lowering of the resolving power. In a double focussing magnetic analyser, ions are passed between a pair of curved plates carrying an electrical charge. These disperse ions according to their kinetic energy but do not separate them according to their m/z values. A magnetic sector will also disperse ions according to their kinetic energies and by placing these two devices together in an appropriate fashion, ions of different energies can be focussed to a single focal point.
Dictionary of Mass Spectrometry by Anthony Mallet